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Caldur® Carbonate hardness CH 5 – Titration

Determination of carbonate hardness in water by titration (0-10 °dH, high resolution)
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Reagent for Caldur® Carbonate hardness CH 5 – Titration:
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CALDUR® Carbonate hardness CH 5 test set – Titration

What is carbonate hardness measured for?

Carbonate hardness (temporary hardness) is an important parameter in water chemistry and provides information about the concentration of hydrogen carbonate and carbonate ions in the water. It is part of the total hardness and plays a decisive role in the buffering capacity of the water (pH stability).

Monitoring carbonate hardness is essential in boiler systems, as carbonate hardness precipitates and forms scale when heated. This impairs heat transfer and can lead to serious damage to the system. The carbonate hardness in boiler water should be as low as possible (< 0.5 °dH). For applications that require particularly high precision in the low hardness range, the CALDUR® CH 5 test set offers a resolution of 0.5 °dH or 0.25 °dH. This is ideal for checking softened water, boiler water and high-purity process water.

How does the test set work?

The CALDUR® carbonate hardness CH 5 test set works according to the proven acid-base titration method. The hydrogen carbonate is neutralized by adding an acid solution drop by drop to a water sample with Reagent. The color changes at the equivalence point – the number of drops used corresponds directly to the carbonate hardness.

The method is simple, fast and provides reliable results in the measuring range from 0 to 10 °dH with a resolution of 0.5 °dH (0.25 °dH with double the sample quantity).

Advantages of the CALDUR® test set

  • Quick analysis in just 1 minute

    Ideal for daily checks in boiler systems and softening systems – immediate results

  • High resolution of 0.5 °dH (or 0.25 °dH)

    Particularly precise measurement in the low hardness range

  • 100 determinations at 5 °dH – economical in continuous use

    Cost-efficient for regular inspections in waterworks and industrial plants

  • Simple drop titration without aids

    No additional devices required – direct reading

  • Clear color change for precise results

    Clearly recognizable end point of the titration

  • Robust, waterproof plastic housing with hinged lid

    Safe transportation and protection of reagents

Areas of application

Pond / lake
Groundwater / well water
Drinking / tap water
Aquaristics
Pool / Swimming pool
Industrial processing
Boiler water
Food preparation
Waste water treatment

Carrying out the measurement:

  1. Fill water sample into test tubes up to the 10 ml mark (for 0.5 °dH resolution) or up to 20 ml (for 0.25 °dH resolution)
  2. Add 1 drop of indicator solution and mix (sample turns green)
  3. Add titration solution drop by drop and shake well after each drop
  4. Count drops until the color changes from green to red/orange
  5. Number of drops × 0.5 = carbonate hardness in °dH (for 10 ml sample)

💡 Tip for best results

For best results, the water sample should be clear and free of suspended solids.
The color change from green to red/orange is clearly visible.
Shake well after each drop to ensure a complete reaction.
For maximum precision, use a 20 ml sample (resolution 0.25 °dH).

⚠️ Important notes

  • Bring reagents to room temperature before use
  • Shake thoroughly after each drop
  • Do not miss the color change – view against a white background if necessary
  • Rinse test tubes thoroughly with distilled water after use
  • Use only 1 drop of Reagent!

Measuring range

Measured value per drop Sample quantity Measuring range
0.5 °dH 10 ml 0 to 10 °dH
0.25 °dH 20 ml 0 to 5 °dH (highest resolution)
💡 Read off intermediate values:
For maximum precision, you can work with a sample volume of 20 ml – each drop then corresponds to 0.25 °dH.

Number of possible provisions

With a CALDUR® test set carbonate hardness CH 5 you can carry out 100 measurements at 5 °dH.
With lower hardnesses, more measurements are possible.

Measuring accuracy and reproducibility

Resolution: 0.5 °dH (with 10 ml sample) or 0.25 °dH (with 20 ml sample)
Reproducibility: Very good if performed carefully
Interferences: No significant interferences for typical water samples

What to do if measured values are out of range?

Measured value > 10 °dH

For carbonate hardness above 10 °dH, we recommend the CALDUR® test set CH with a measuring range up to 20 °dH.
Alternatively, you can dilute the sample:

Dilution Procedure Calculation of the measured value
1:1 5 ml sample + 5 ml distilled water Number of drops × 1.0 = °dH

Specifications at a glance

Property Value
Parameters Carbonate hardness (CH)
Item number 31-071430
Method Acid-base titration
Measuring principle Droplet titration with color change
Measuring range 0 to 10 °dH
Resolution 0.5 °dH or 0.25 °dH
Analysis duration 1 minute
Number of determinations 100 at 5 °dH
Packaging Hinged lid box
Packaging size 103 x 91 x 36 mm
weight approx. 130 g
Scope of delivery
1 titration solution (30 ml)
1 indicator solution (5 ml)
1 test tube with 10 ml / 20 ml scale
Detailed operating instructions (DE/EN)
Safety data sheets
Robust hinged lid box (103 x 91 x 36 mm)

Reagent details

Reagent Volume Shelf life Notes
Titration solution 30 ml 36 months (36M) Shake before use
Indicator solution 5 ml 36 months (36M) Shake before use, use 1 drop

Shelf life: The shelf life starts from the date of manufacture (printed on the bottle).
After opening, the reagents should be used within 12 months.
Store the test kit in a dry, cool place (10-25°C) and away from direct sunlight.

Additional information

Packaging

Hinged lid box

Flyer
Operating instructions

Instructions for use

Instructions for use