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Caldur® DEHA (diethylhydroxylamine) – Colorimetric

DEHA determination (diethylhydroxylamine) in boiler water by color chart (0.05-1.0 mg/l)
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Reagent for Caldur® DEHA (diethylhydroxylamine) – Colorimetric:
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CALDUR® DEHA (Diethylhydroxylamine) test kit – Colorimetric

What is DEHA measured for?

DEHA (diethylhydroxylamine) is a highly effective oxygen binding agent that plays a central role in boiler water treatment and industrial steam generation. As an organic hydrazine substitute, DEHA binds dissolved oxygen in feed water and thus effectively prevents corrosion in steam boilers, pipelines and heat exchangers. Unlike hydrazine, DEHA is not carcinogenic and is therefore the preferred choice for modern boiler systems.

The typical dosage is between 0.1 and 0.5 mg/l DEHA, depending on the oxygen content of the feed water and the specific operating conditions. Regular monitoring of the DEHA concentration is essential to ensure adequate corrosion protection on the one hand and to avoid overdosing on the other. Too low DEHA values lead to insufficient corrosion protection, while too high concentrations are economically inefficient and can affect the pH value of the boiler water.

DEHA reacts with oxygen and forms acetic acid and nitrogen as reaction products. This reaction takes place at low temperatures and is accelerated at higher temperatures, which makes DEHA particularly suitable for low-pressure boilers and hot water systems.

How does the test set work?

The CALDUR® DEHA test set – Colorimetric works according to the proven ferrozine method. DEHA reduces trivalent iron ions (Fe³⁺) to divalent iron ions (Fe²⁺), which then form a violet color complex with the ferrozine reagent. The intensity of the coloration is directly proportional to the DEHA concentration in the water sample.

After adding two reagents to the water sample, a characteristic violet coloration develops within 5 minutes. The measured value is determined by direct color comparison with a 6-stage color chart provided. This colorimetric method enables fast and reliable on-site analysis without the need for expensive laboratory equipment.

Advantages of the CALDUR® test set

  • Quick analysis in just 5 minutes

    Ideal for daily routine checks in boiler plants and steam generation systems

  • High precision in the relevant concentration range (0.05 – 1.0 mg/l)

    Perfect for monitoring the optimum DEHA dosage in boiler water

  • 100 provisions per set – economical in continuous use

    Cost-efficient for regular inspections in power plants and industrial steam systems

  • Can be used colorimetrically – no additional devices required

    Flexible for simple on-site tests directly on the boiler system

  • Easy handling without special equipment

    No additional technology required – ideal for operating personnel

  • Robust, waterproof plastic housing with hinged lid

    Safe transportation and protection of reagents – durable and reliable

Areas of application

Pond / lake
Groundwater / well water
Drinking / tap water
Aquaristics
Pool / Swimming pool
Industrial processing
Boiler water
Food preparation
Waste water treatment

Carrying out the measurement:

  1. Fill water sample into test tube up to the 10 ml mark
  2. Add 5 drops of reagent A and mix
  3. Add 5 drops of reagent B and mix
  4. Wait for 5 minutes reaction time
  5. Perform color comparison with color chart

Tip for best results

The water sample should be brought to room temperature before the measurement.
If the boiler water is heavily colored, a blank value determination with distilled water is recommended.

Important notes

  • Take the sample as fresh as possible and analyze it immediately
  • Bring reagents to room temperature before use
  • Adhere exactly to the reaction time of 5 minutes
  • Avoid direct sunlight during the measurement
  • Rinse test tubes thoroughly with distilled water after use

Measuring range

Measuring level Description
0.05 mg/l Very low concentration (light violet)
0.1 mg/l Low concentration (light violet)
0.25 mg/l Optimum concentration (violet)
0.5 mg/l Average concentration (violet)
0.75 mg/l Elevated concentration (dark violet)
1.0 mg/l High concentration (dark violet)
Read intermediate values:
If the color lies between two fields, you can form the mean value
(e.g. between 0.25 and 0.5 mg/l = approx. 0.35-0.4 mg/l).

Number of possible provisions

You can carry out 100 measurements with one CALDUR® DEHA test set.
This refers to the quantity of reagents contained.

Measuring accuracy and reproducibility

Readability: ± 1 color level
Reproducibility: Very good if the application instructions are followed
Interference: Other reducing agents such as Sulfite or hydrazine can influence the result. High concentrations of iron in the sample should be taken into account.

What to do if measured values are out of range?

Measured value > 1.0 mg/l

Dilution Procedure Calculation of the measured value
1:1 5 ml sample + 5 ml distilled water Measured value × 2
1:4 2 ml sample + 8 ml distilled water Measured value × 5

Measured value < 0.05 mg/l

Measured value is below the detection limit. This may indicate insufficient DEHA dosing – check the dosing system and increase the dosing quantity if necessary.

Specifications at a glance

Reagents (reagent A, B)

Property Value
Parameters DEHA (diethylhydroxylamine, C₄H₁₁NO)
Item number 31-072300
Method Colorimetric (ferrozine)
Measuring principle Color comparison with 6-stage color chart
Measuring range 0.05 to 1.0 mg/l DEHA
Color scale 6 measuring levels (0.05 / 0.1 / 0.25 / 0.5 / 0.75 / 1.0 mg/l)
Duration of analysis 5 minutes
Number of provisions 100
Packaging Hinged lid box
Packaging size 103 x 91 x 36 mm
weight approx. 150 g
Scope of delivery
2 reagent bottles (reagent A, B) with detailed labeling
1 test tube with 10 ml scale
1 color card with 6 measuring levels
Detailed operating instructions (DE/EN)
Safety data sheets for all reagents
Robust hinged lid box (103 x 91 x 36 mm)

Reagent details

Reagent Volume Shelf life Notes
Reagent A 15 ml 48 months (48M) Ferrozine solution, shake before use
Reagent B 15 ml 48 months (48M) Buffer solution, shake before use

Shelf life: The shelf life starts from the date of manufacture (printed on the bottle).
After opening, the reagents should be used within 12 months.
Store the test kit in a dry, cool place (10-25°C) and away from direct sunlight.

Additional information

Packaging

Hinged lid box, Refill pack

Flyer
Operating instructions

Instructions for use

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31-072200 Testkit Aluminium DE/ENG.pdf 294.03 KB 413 downloads

Instructions for use

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31-072200 Testkit Aluminium DE/ENG.pdf 294.03 KB 413 downloads