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Caldur® Total hardness GR – Titration

Total hardness determination in water by titration (0.1 / 0.05 °dH per drop)
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Reagent for Caldur® Total hardness GR – Titration:
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CALDUR® Total Hardness Test Set GR – Titration

What is the total hardness measured for?

The total hardness of water is an important parameter for water quality and describes the sum of all alkaline earth ions, mainly calcium (Ca²⁺) and magnesium (Mg²⁺). These ions originate from the natural dissolution of rocks and minerals and have a significant influence on the properties of the water.

In Germany, water hardness is given in °dH (degrees of German hardness):

  • 0-7 °dH: Soft water
  • 7-14 °dH: Medium hard water
  • 14-21 °dH: Hard water
  • >21 °dH: Very hard water

Knowing the water hardness is crucial for many applications: from the dosing of detergents and the adjustment of softening systems to the prevention of limescale deposits in pipes, boilers and industrial systems.

Hardness measurement is particularly important for: Drinking water treatment, boiler water monitoring, aquaristics, swimming pools, the food industry and industrial processes.

How does the test set work?

The CALDUR® Total Hardness Test Set GR uses the proven complexometric titration method with EDTA (ethylenediaminetetraacetic acid). In this method, the calcium and magnesium ions are bound by EDTA, with a Reagent indicating the end point by a characteristic color change.

Measuring principle: 1 reagent is added to the water sample. When the titration solution is added drop by drop, the hardness constituents bind to the EDTA. The color change from red to green indicates that all hardness constituents are bound.

Calculation: Each drop of titration solution corresponds to 0.1 °dH (for 5 ml sample) or 0.05 °dH (for 10 ml sample). The number of drops multiplied by the drop value directly results in the total hardness in °dH.

Advantages of the CALDUR® test set

  • Quick analysis in just 1 minute

    Ideal for routine checks on site – immediate results without waiting time

  • High precision due to drop-by-drop titration

    Measured value per drop: 0.1 / 0.05 °dH – exact results thanks to proven complexometric method

  • 100 at 1°dH Determinations per set

    Economical for regular household, commercial and industrial checks

  • Clear color change from red to green

    Clear endpoint recognition – easy to read even for inexperienced users

  • Flexible sample volume (5 ml or 10 ml)

    Higher accuracy with 10 ml sample due to halved drop value

  • Robust, waterproof plastic housing with hinged lid

    Safe transportation and protection of reagents – durable even under harsh conditions

Areas of application

Pond / lake
Groundwater / well water
Drinking / tap water
Aquaristics
Pool / Swimming pool
Industrial processing
Boiler water
Food preparation
Waste water treatment

Carrying out the measurement:

  1. Fill water sample into test tubes up to the 5 ml or 10 ml mark
  2. Titration solution already contains the Reagent
  3. Add titration solution drop by drop with constant swirling
  4. Count drops until the color clearly changes from red to green
  5. Calculate measured value: Number of drops × drop value = °dH

Tip for best results

For a clear color change, the water sample should be clear.
With a sample volume of 10 ml, you will obtain more accurate measured values (halved drop value).
The color change from red to green indicates the end of the titration.
A white background helps if the color change is difficult to see.

Important notes

  • Bring reagents to room temperature before use
  • Dispense drops evenly and vertically from the bottle
  • Mix well after each drop and check for color change
  • Rinse test tubes thoroughly with distilled water after use
  • For red-green visual impairment: Use test set GH 100 red-blue (item no. 31-091310)

Measuring range

Number of drops Total hardness
1 drop 0.1 °dH (5 ml) / 0.05 °dH (10 ml)
5 drops 0.5 °dH (5 ml) / 0.25 °dH (10 ml)
10 drops 1.0 °dH (5 ml) / 0.5 °dH (10 ml)
20 drops 2.0 °dH (5 ml) / 1.0 °dH (10 ml)
50 drops 5.0 °dH (5 ml) / 2.5 °dH (10 ml)
Tip: When using a 10 ml sample volume, the drop value is halved, which enables a more accurate measurement.

Calculation: Measured value (°dH) = number of drops × drop value

Number of possible provisions

With a CALDUR® test set total hardness GR you can test 100 at 1°dH.
This refers to the quantity of reagents contained.

Measuring accuracy and reproducibility

Readability: ± 0.1 (per drop for 5 ml sample)
Reproducibility: Very good if application instructions are followed and color perception is good
Interference: High concentrations of copper, zinc or iron can interfere with the measurement. Dilution is recommended for strongly colored samples.

Specifications at a glance

Property Value
Parameters Total hardness (Ca²⁺ + Mg²⁺)
Item number 31-071330
Method Titrimetric (complexometric)
Measuring principle Drop counting until color change (red → green)
Measured value per drop 0.1 / 0.05 °dH
Analysis duration 1 minute
Number of determinations 100 at 1°dH
Description 1 reagent, complexometric titration
Packaging Hinged lid box / folding box
Packaging size 103 x 91 x 36 mm (hinged lid box) / 65 x 45 x 25 mm (folding box)

Scope of delivery

Component Component description
Titration solution 30 ml bottle with dropper insert (contains Reagent)
1 test tube With 5 ml and 10 ml marking
Operating instructions Detailed in DE/EN
Packaging Robust hinged lid box or folding box

Reagent details

Reagent Volume Shelf life Notes
Titration solution (with Reagent) 30 ml 36 months (36M) Dropper bottle, shake before use

Shelf life: The shelf life starts from the date of manufacture (printed on the bottle).
After opening, the reagents should be used within 12 months.
Store the test kit in a dry, cool place (10-25°C) and away from direct sunlight.

Additional information

Packaging

Folding box, Hinged lid box

Flyer
Operating instructions

Instructions for use

Instructions for use